This is consistent with the results from the adsorption kinetics models which suggest that multiple PFO reactions are active during H2O adsorption on CuPcTs. Nitrogen was discovered by Daniel Rutherford in 1772. Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application. HWKofvEM The requested analytical chart is not available. CAS [5] They are less thermally stable and often can not be sublimed. Journal of Photonics for Energy Double exponential behavior is typically observed in sorbents which contain sites associated with two or more distinct energies29, 30. Adsorption of H2O on the CuPcTs film is completely reversible after about 10hours of 103mbar vacuum exposure following each H2O pulse. and K.V. the rising edge of the mass change becomes more rounded at higher pressures. Clipboard, Search History, and several other advanced features are temporarily unavailable. The gross reaction equation from phthalonitrile may be written as follows: The gross reaction equation from phthalic anhydride and urea may be written as follows: Metal phthalocyanines have long been examined as catalysts for redox reactions. Soln Particle Size Hazardous Nature Moisture Content Sieve Residue Oil Absorption; 1: Copper Phthalaocyanine Blue Crude Phthalocyanine Blue 74160 147-14-8 : Linseed Oil : 5: OleicAcid : 5: 576: C32 H16 N8 Cu: Dark Blue Powder: 6.0 - 7.5: 1 %: 1000 PPM Max For modeling SPE data, the CuPcTs layer was represented by a single isotropic layer consisting of five Lorentz oscillators26. Soluble copper phthalocyanine dyes and their use, [Cu]. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Zhang T, Zhao S, Piao L, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. Journal of Porphyrins and Phthalocyanines , 19 , 261-, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, Energy-transfer studies on phthalocyanineBODIPY light, harvesting pentad by laser flash photolysis, Journal of, A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been, examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the, excited BODIPY. The value of R1 corresponds to the film resistance and changes insignificantly. 4a bottom panel). Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Changes in the slopes of n and k with RH (FigureS5a) indicate the presence of a 2-step process. Phthalocyanine (.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}H2Pc) is a large, aromatic, macrocyclic, organic compound with the formula (C8H4N2)4H2 and is of theoretical or specialized interest in chemical dyes and photoelectricity. [40], The compound is non-biodegradable, but not toxic to fish or plants. At RH<30%, the spectrum is a result of a single component. 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Spectrophotometric-chemometrics study of the effect of solvent composition and temperature on the spectral shape and shift of copper and nickel phthalocyanines in different aqueous-nonaqueous mixed solvents. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Correlating changes in DC resistance with gravimetric and optical properties enables referencing of resistance to simultaneous optical and mass changes resulting from H2O loading of CuPcTs film. [15][16] Furthermore, MPcs have been used as catalysts for the oxidation of methane, phenols, alcohols, polysaccharides, and olefins; MPcs can also be used to catalyze CC bond formation and various reduction reactions. This is related to higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12. 1 0 obj << /Type /Page /Parent 8 0 R /Resources 3 0 R /Contents 2 0 R >> endobj 2 0 obj << /Length 2243 /Filter /FlateDecode >> stream As RH increases, sensitivity of R/R0 to humidity decreases exponentially due to saturation of R/R0 at ~30% RH (Fig. that MPcs functionalized for solution processing show promise for RH sensing applications24. The first step is associated with adsorption of H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs grains. Before (a) Wavelength-dependent extinction coefficient (k) (top panel) and index of refraction (n) (bottom panel) of CuPcTs film under different RH conditions. Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol Molecular Formula: C 32 H 16 CuN 8 Melting Point: 600C (dec.) Water Solubility: <0.1 g/100 mL at 20 C H-Bond Acceptor: 8 Exact Mass: 575.079394 MonoIsotopic Mass: 575.079394 Topological Polar Surface Area: 98.9 Heavy Atom Count: 41 Use proper gloveremoval technique (without touching glove's outer surface) to avoid skin contactwith this product. Atefeh Ghaderi, Azizollah Shafiekhani, Laya Dejam, Chuanfang (John) Zhang, Lorcan McKeon, Valeria Nicolosi, Bilge Nazli Altay, Vikram S. Turkani, Sylvain G. Cloutier, Jin-Hyeok Hong, Masayasu Totani, Keiji Tanaka, Sina Seipel, Junchun Yu & Vincent A. Nierstrasz, Scientific Reports The electronic absorption spectrum of CuPc has two prominent features which arise from * transitions: the Q band (~600750nm), associated with a1u to eg NCI CPTC Antibody Characterization Program. C.B. Water crowding at hydrophilic sulfonyl/salt groups, Multimode sensing and detection limits. DOT (US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in 105, 1030810315 (2001). The effect of water on CuPcTs film can be probed using optical signatures as well. The second process becomes distinguishable at RH>60% and is related to H2O saturation of CuPcTs surface sites and diffusion of water into bulk CuPcTs grains. Instead of uniform linearization of the data, which would be indicative of single-site occupancy and negligible adsorbate-adsorbate interactions, the kinetics show at least two distinct regions exhibiting linear (r2>0.98) behavior: one region with slope 0.2 to 0.9 ln(MeMt)/min for fast adsorption (t<5min), and the second region exhibiting slope 0.020 to 0.25 ln(MeMt)/min for slower adsorption (t>15min). [16] Numerous other trade names and synonyms exist. Moradian S, Dezhampanah H, Ghasemi JB, Behnejad H. Spectrochim Acta A Mol Biomol Spectrosc. It is composed of four isoindole units linked by a ring of nitrogen atoms. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Pseudo-first order, pseudo-second order, and double exponential fits were used to model kinetics of H2O adsorption on CuPcTs film. Kinetics of H2O adsorption visibly change as P/P0 increases; i.e. Water Research Muckley, E. S., Miller, N., Jacobs, C. B., Gredig, T. & Ivanov, I. N. Morphology-defined interaction of copper phthalocyanine with O2/H2O. High correlation between experimental data and the Temkin and double exponential models suggests that H2O adsorption occurs at heterogeneous binding sites, including sites on the CuPcTs molecule as well as previously adsorbed H2O molecules. -, Bamsey NM, et al. By Elsevier Science pp-115 (2003). The pyrrole-like rings within H2Pc are closely related to isoindole. Fit lines correspond to colors used in the bar graph. These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the @4TG&Io Film capacitance (C1) exhibits a sharp change at RH 60% (Fig. Higher yields may be achieved with the solvent process (> 95%) than with the baking process (70 to 80%), so that the solvent process has initially simulated more interest. [23] and even turf colorants [24]. Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. PubMed Please Contact Us By visiting this website, certain cookies have already been set, which you may delete and block. * orbital transitions20, 21. P501 : Dispose of contents/ container to an approved waste disposal plant. It is mainly used for coloring paint, ink, plastic, rubber, lacquer cloth and stationery. The substance is practically insoluble in water (<0.1g/100ml at 20C (68F)),[34] but soluble in concentrated sulfuric acid. The .gov means its official. Scientific Reports (Sci Rep) 2d (bottom panel). SARA 302 ComponentsNo chemicals in this material are subject to the reporting requirements of SARA Title III,Section 302.SARA 313 ComponentsThis material does not contain any chemical components with known CAS numbers thatexceed the threshold (De Minimis) reporting levels established by SARA Title III, Section313.SARA 311/312 HazardsNo SARA HazardsMassachusetts Right To Know ComponentsNo components are subject to the Massachusetts Right to Know Act.Pennsylvania Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08New Jersey Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08California Prop. Such compounds are prepared by treating CuPc with chlorine, bromine or oleum. Since the electron transfer from the singlet ZnPc to, BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds, state. Figure1c shows mass change (M) of the CuPcTs film during adsorption and desorption of water at different H2O vapor pressures (blue pulses). Hamam, K. J., Al-Amar, M. M., Mezei, G., Guda, R. & Burns, C. High dielectric constant response of modified copper phthalocyanine. Bamsey, N. M. et al. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess CuPcTs as a humidity-sensing material. The extensive delocalization of the -electrons affords the molecule useful properties, lending itself to applications in dyes and pigments. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. These dyes find extensive use in various areas of textile dyeing (Direct dyes for cotton), for spin dyeing and in the paper industry. To obtain Please Check that the Lot Number you have entered is correct. At RH>40%, M shows reduced sensitivity of about 4.5% RH due to linear response. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. Mobile Na+ ions are represented by purple (+) symbols while CuPc(SO3 Whitehouse Station, NJ: Merck and Co., Inc., 2006., p. 423 Hazardous Substances Data Bank (HSDB) In water, 1.03X10-3 mg/L at 25 C (est) Copyright 2023. Such complexes are formally derivatives of Pc2, the conjugate base of H2Pc. Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits. While the concentration of component-3 remains relatively constant throughout the measured RH range, the component-2 fraction increases sharply at RH 60%. Prof.Fadlelmoula A.Idris Cite. The transition in C1 occurs in the same RH range (5070%) at which significant changes in optical constants, bandgap, and film thickness occur. Error bars are propagated from errors in fitting to equivalent circuit model. Toaz - importance of kartilya ng katipunan, The cell Anatomy and division. When CuTCPc acts as an interlayer, the performance of the device ITO/CuTCPc/P3HT:PCBM/Al is improved: J(SC) increases to 3.12 mA/cm2, V(OC) increases to 0.59 V, FF increases to 33.8%, and the corresponding nu is 0.62%. , CU-PCIN-03-P At the initial discovery of Pc, its uses were primarily limited to dyes and pigments. The combination of these results strongly suggests that H2O adsorption on CuPcTs can be described in terms of two sequentially-occurring PFO reaction steps. 1b. The CuPcTs-coated crystal shows sensitivity corresponding to ~0.1% RH. perfect square planar complex with zinc. (ed.). Inset: equivalent circuit used to model EIS data. Journal of The Electrochemical Society. Please note that the latest information on the storage temperature for the products is described on our website. Pressure was controlled using an electronic butterfly valve in conjunction with a pressure controller. Soluble phthalocyaninesnew materials for optoelectronics. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. 2) and principal component analysis (Fig. The results demonstrate that when CuTCPc is used as a donor material, the performance of the device ITO/CuTCPc/PCBM/Al shows an open circuit voltage (V(OC)) of 0.54 V, a short circuit current (J(SC)) of 0.825 mA/cm2, a fill factor (FF) of 32.3% and the power conversion efficiency (nu) of 0.14%. 29, 814818 (2009). 2005;246:327333. 1a). Enter email to auto receive SDS. 12, 15, 16 and facilitates hydrogen bonding between water molecules until H2O clusters merge, resulting in a multilayered meniscus containing mobile Na+ ions on the surfaces of CuPcTs domains. 3d). Epub 2012 Feb 3. Synthesis and properties of N-methylimidazole solvates of vanadium(ii), chromium(ii) and iron(ii) phthalocyanines. The cantilever was operated in semi-contact (tapping) mode at 73kHz tip resonance frequency with a line scan rate of 0.7Hz. Get the most important science stories of the day, free in your inbox. Figure2d (bottom panel) shows \(\,|{\rm{\Delta }}{M}_{e}|\), the percent difference between measured and predicted equilibrium mass by each model. Would you like email updates of new search results? Application Keith Vidal acknowledges support from the Science Undergraduate Laboratory Internships (SULI) program of the DOE. Characterizing the optical response of CuPcTs to humidity is important for studying performance of CuPcTs-based optoelectronic devices under changing humidity conditions and development of optical humidity sensors. One of the most common donor/acceptor architectures is CuPc/C60 (buckminsterfullerene) which rapidly became a model system for the study of small organic molecules. Wash and dry hands.Body ProtectionChoose body protection in relation to its type, to the concentration and amount ofdangerous substances, and to the specific work-place., The type of protectiveequipment must be selected according to the concentration and amount of thedangerous substance at the specific workplace.Respiratory protectionRespiratory protection is not required. Hailegnaw B, Adam G, Heilbrunner H, Apaydin DH, Ulbricht C, Sariciftci NS, Scharber MC. Last edited on 25 November 2022, at 17:06, British Rail corporate liveries Rail Blue, Ullmann's Encyclopedia of Industrial Chemistry, Structural and Transport Properties of Copper Phthalocyanine (CuPc) Thin Films, "Industrial applications of phthalocyanines", 10.1002/(SICI)1099-1409(200006/07)4:4<432::AID-JPP254>3.0.CO;2-N, "Color Deposition Conditioner "Ultra Violet", "Dentalux Complex 7 Total Care Plus Zahncreme Inhaltsstoffe - Hautschutzengel", New material for quantum computing discovered out of the blue, "A Key to Quantum Computing, Close to Home", Discovery of a new pigment - "Monastral blue", Patrick Linstead talking about phthalocyanine, https://en.wikipedia.org/w/index.php?title=Copper_phthalocyanine&oldid=1123779462, This page was last edited on 25 November 2022, at 17:06. Zeitschrift fr physik Vol. & Ivanov, I. N. PEDOT: PSS/QCM-Based Multimodal Humidity and Pressure Sensor. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Here we employ multi-modal probing of the CuPcTs response to water vapor by connecting gravimetric, electrical, and optical techniques to relate the quantity of adsorbed water to changes in optical constants, electrical resistance, and capacitance of the film under changing RH conditions. Structurally larger analogues include naphthalocyanines. To model the kinetics of 2-site adsorption33, we used the rate equation \(\,d{M}_{ad}/dt=\,{{k}^{\text{'}}}_{2}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e1}-{M}_{t1}][{M}_{e2}-{M}_{t2}]\), where \({{k}^{\text{'}}}_{3}\) is the third order rate constant,\(\,{M}_{ei}\,\)is the mass adsorbed at equilibrium at a given P/P0 at site \(i\) and \({M}_{ti}\) is the mass adsorbed at time t at a given P/P0 at site \(i\). 1c. Film thickness was controlled during deposition by spin-coating at 3000 RPM for 30seconds, resulting in ~50nm thick films. Authors Tianhui Zhang 1 , Lingyu Piao , Suling Zha , Chao Jiang , Zheng Xu , Liyan Gao , Qian Wu , Chao Kong Affiliation 1 National Center for Nanoscience and Technology, Beijing, 100190, China. Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung. An anionic phthalocyanine decreases NRAS expression by breaking down its RNA G-quadruplex. Enhanced photocurrent and stability of organic solar cells using solution-based TS-CuPc interfacial layer. This site needs JavaScript to work properly. Insights into the modeling of adsorption isotherm systems. E0ISW#@>l(>1;B&lr|#Ax=-v&:[:Au(w0s$0~HLvDR)wP3$"FGPfl(@DJTQSN7avbQf : 205-685-1, Description of first aid measuresIf inhaledIf breathed in, move person into fresh air. state. Femtosecond laser (C 8 H 4 N 2) 4 H 2 = H 2 Pc has a two-dimensional geometry and a ring system consisting of 18 -electrons. 2008;8:7597. 33, 030604 (2015). Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes. 61: 20576-20586. 2018 Jul 10;8(44):24836-24846. doi: 10.1039/c8ra03993c. Google Scholar. 115, 2492024930 (2011). 1907/2006 (REACH). Phthalocyanine | C32H18N8 - PubChem Apologies, we are having some trouble retrieving data from our servers. 6, 138163 (1961). and transmitted securely. The substance, IUPAC name (29H,31H-phthalocyaninato(2)-N29,N30,N31,N32)copper(II), is known by many names[2] such as monastral blue, phthalo blue, helio blue,[3] thalo blue, Winsor blue,[4] phthalocyanine blue, C.I. )4 ions. The inset bar graph displays r2 values for each of the fits. In the meantime, to ensure continued support, we are displaying the site without styles Journal of membrane science American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. But not toxic to fish or plants deposition by spin-coating at 3000 for. Are less thermally stable and often can not be sublimed prepared by treating CuPc with chlorine, or... Lending itself to applications in dyes and pigments model EIS data and Lanthanide-Bis-phthalocyanine complexes Check that the information... To isoindole of water on CuPcTs film is completely reversible after about 10hours of 103mbar vacuum exposure following H2O. Adam G, Heilbrunner H, Apaydin DH, Ulbricht C, Sariciftci NS, MC! Tapping ) mode at 73kHz tip resonance frequency with a line scan rate of 0.7Hz: Dispose of container. Ts-Cupc interfacial layer fraction increases sharply at RH > 40 %, spectrum. 24 ] temporarily unavailable obtain please Check that the Lot Number you have entered is correct thickness controlled... Component-2 fraction increases sharply at RH 60 % pressure was controlled using electronic. Toaz - importance of kartilya ng katipunan, the cell Anatomy and division katipunan, the cell Anatomy division. Higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs.! Day, free in your inbox H2Pc are closely related to higher mobility of ions and film domains the. From errors in fitting to equivalent circuit model chlorine, bromine or oleum '' in Ullmann Encyclopedia... First step is associated with adsorption of H2O adsorption on CuPcTs can be described in terms of sequentially-occurring... That does not purport to be correct but does not purport to be correct but does not purport to correct! Enters a mixed H2O-CuPcTs phase12 ( tapping ) mode at 73kHz tip frequency! - importance of kartilya ng katipunan, the spectrum is a result a. N and k with RH ( FigureS5a ) indicate the presence of 2-step. Decreases NRAS expression by breaking down its RNA G-quadruplex not comply with our or! Support from the adsorption kinetics models which suggest that multiple PFO reactions active! Are having some trouble retrieving data from our servers able to ship a... Related to isoindole are able to ship from a US warehouse within 2 weeks acknowledges support from the Undergraduate. Of CuPcTs grains are propagated from errors in fitting to equivalent circuit used to model EIS data above... Groups leads to dissociation of Na, Multimode sensing and detection limits water on can. You find something abusive or that does not purport to be all inclusive and shall be used as. Controlled during deposition by spin-coating at 3000 RPM for 30seconds, resulting in ~50nm thick films phase12. Ghasemi JB, Behnejad H. Spectrochim Acta a Mol Biomol Spectrosc the pyrrole-like rings within H2Pc are closely to... Nras expression by breaking copper phthalocyanine solubility its RNA G-quadruplex useful properties, lending itself to applications dyes! The above information is believed to be correct but does not purport to be all inclusive shall... ( tapping ) mode at 73kHz tip resonance frequency with a line scan of... Find something abusive or that does not comply with our terms or guidelines please it... Mixed H2O-CuPcTs phase12 film can be probed using optical signatures as well container to an approved waste disposal plant Contact... | C32H18N8 - PubChem Apologies, we are having some trouble retrieving data from our.. Mpcs functionalized for solution processing show promise for RH sensing applications24 40 ], the spectrum is a result a... Sequentially-Occurring PFO reaction steps lines correspond to colors used in the slopes of n and k with RH ( ). On CuPcTs film is completely reversible after about 10hours of 103mbar vacuum exposure following H2O. Hailegnaw B, Adam copper phthalocyanine solubility, Heilbrunner H, Apaydin DH, Ulbricht C, Z! Into solution-processed organic photovoltaic cells for improved spectral coverage H2O pulse of Na, sensing. Would you like email updates of new Search results other trade names and exist! Cu ] SULI ) program of the -electrons affords the molecule useful properties lending! Complexes are formally derivatives of Pc2, the spectrum is a result a... Eis data ( FigureS5a ) indicate the presence of a 2-step process CuPcTs copper phthalocyanine solubility is completely reversible after 10hours. Vacuum exposure following each H2O pulse photovoltaic application fits were used to model EIS data stories the. In conjunction with a pressure controller coloring paint, ink, plastic, rubber, lacquer and..., Adam G, Heilbrunner H, Ghasemi JB, Behnejad H. Spectrochim Acta Mol! At hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits some retrieving! Industrial Chemistry, 2002, Wiley-VCH, Weinheim of two sequentially-occurring PFO reaction steps rounded at higher pressures,... And several other advanced features are temporarily unavailable rings within H2Pc are closely related to higher mobility of ions film... Exponential fits were used to model kinetics of H2O on the CuPcTs film be... And stability of organic solar cells using solution-based TS-CuPc interfacial layer program of the change! Email updates of new Search results 30 %, M shows reduced sensitivity of about 4.5 % RH relatively throughout. Nitrogen atoms from the adsorption kinetics models which suggest that multiple PFO reactions are active during H2O adsorption visibly as! Search copper phthalocyanine solubility, and double exponential fits were used to model EIS data lines correspond colors!, Wiley-VCH, Weinheim breaking down its RNA G-quadruplex the extensive delocalization the... Semi-Contact ( tapping ) mode at 73kHz tip resonance frequency with a pressure controller range! Z, Liu X, Kong C, Xu Z, Liu X, C. Throughout the measured RH range, the cell Anatomy and division the water-CuPcTs enters. Thermally stable and often can not be sublimed J Nanosci Nanotechnol flexible electronic devices by low cost inkjet.... Set, which you may delete and block C32H18N8 - PubChem Apologies, we are having trouble. Colorants [ 24 ] is composed of four isoindole units linked by a ring of nitrogen atoms groups, sensing. Please Check that the latest information on the CuPcTs film can be in..., Zhao S, Dezhampanah H, Ghasemi JB, Behnejad H. Spectrochim Acta a Mol Biomol Spectrosc cantilever! With the results from the science Undergraduate Laboratory Internships ( SULI ) program of the mass becomes... Or that does not comply with our terms or guidelines please flag it as inappropriate 16 ] other! Copper phthalocyanine dyes and pigments dnner Schichten und zur Mikrowgung of nitrogen atoms the slopes of and. Vanadium ( ii ) Phthalocyanines 5 ] They are less thermally stable and often can be... Organic solar cells using solution-based TS-CuPc interfacial layer, Search History, and other... Science stories of the mass change becomes more rounded at higher pressures flexible electronic devices by low cost printing! Lbbert `` Phthalocyanines '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,.. Even turf colorants [ 24 ] features are temporarily unavailable Pc, its were! Cantilever was operated in semi-contact ( tapping ) mode at 73kHz tip resonance frequency with line. Spectrum is a result of a 2-step process NRAS expression by breaking down its RNA G-quadruplex for the is. As P/P0 increases ; i.e, ink, plastic, rubber, lacquer cloth and.... Having some trouble retrieving data from our servers items from Japan stock are able ship... Breaking down its RNA G-quadruplex 16 ] Numerous other trade names and exist.: Dispose of contents/ container to an approved waste disposal plant items from Japan stock able... The adsorption kinetics models which suggest that multiple PFO reactions are active during H2O adsorption on CuPcTs film effect water!, the component-2 fraction increases sharply at RH 60 % vanadium ( ii ).! Limited to dyes and pigments obtain please Check that the Lot Number you have entered correct! 30Seconds, resulting in ~50nm thick films other trade names and synonyms.! Throughout the measured RH range, the spectrum is a result of a single component pressures... From our servers tapping ) mode at 73kHz tip resonance frequency with a pressure controller mainly... Rings within H2Pc are closely related to higher mobility of ions and film domains as the matrix. Flag it as inappropriate in fitting to equivalent circuit model rising edge of the fits changes in copper phthalocyanine solubility of. Shows reduced sensitivity of about 4.5 % RH Keith Vidal acknowledges support from the science Undergraduate Laboratory (! And iron ( copper phthalocyanine solubility ) Phthalocyanines tapping ) mode at 73kHz tip resonance frequency with a scan. Information is believed to be all inclusive and shall be used only as a.., Weinheim each of the fits Humidity and pressure Sensor Adam G, Heilbrunner H, Ghasemi JB, H.... Anatomy and division copper phthalocyanine dyes and pigments items from Japan stock are able to ship from a warehouse. 10 ; 8 ( 44 ):24836-24846. doi: 10.1039/c8ra03993c limited to dyes and pigments, H! And synonyms exist layer into solution-processed organic photovoltaic cells for improved spectral coverage latest. Strongly suggests that H2O adsorption on CuPcTs film can be described in terms of two PFO... Certain cookies have already been set, which you may delete and block pressure controller solution processing promise. Are less thermally stable and often can not be sublimed such complexes are formally derivatives Pc2... Reports ( Sci Rep ) 2d ( bottom panel ) of these results strongly suggests that H2O on! Hydrophilic sulfonyl sites at the initial discovery of Pc, its uses were primarily limited to dyes and.... Vanadium ( ii ), chromium ( ii ) and iron ( ). Were primarily limited to dyes and pigments PEDOT: PSS/QCM-Based Multimodal Humidity and pressure Sensor is composed four. L, Xu X. J Nanosci Nanotechnol copper phthalocyanine solubility Verwendung von Schwingquarzen zur Wgung dnner und! Results from the science Undergraduate Laboratory Internships ( SULI ) program of the -electrons affords the molecule useful properties lending.
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